{"id":4964,"date":"2025-01-29T03:13:27","date_gmt":"2025-01-29T00:13:27","guid":{"rendered":"https:\/\/jrn.isi.gov.ua\/?page_id=4964"},"modified":"2026-03-28T01:20:01","modified_gmt":"2026-03-27T22:20:01","slug":"doi-10-52150-2522-9117-2024-38-146-167","status":"publish","type":"page","link":"https:\/\/jrn.isi.gov.ua\/?page_id=4964&lang=en","title":{"rendered":"DOI: 10.52150\/2522-9117-2024-38-146-167"},"content":{"rendered":"\n<p><strong>Yelisieiev Volodymyr Ivanovych<\/strong>, Ph. D. (Pys.-Math.), Senior Researcher, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, Academican Starodubova Square, 1, Dnipro, 49107, Ukraine. ORCID: 0000-0003-4999-8142. E-mail: ovoch-isi@outlook.com<\/p>\n\n\n\n<p><strong>Manachyn Ivan Oleksandrovych<\/strong>, Ph. D. (Tech.), Senior Researcher, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, Academican Starodubova Square, 1, Dnipro, 49107, Ukraine. ORCID: 0000-0001-9795-6751. E-mail: ovoch-isi@outlook.com<\/p>\n\n\n\n<p><strong>Molchanov Lavr Serhiiovych<\/strong>, Ph. D. (Tech.), Head of Department, Senior Researcher, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, Academican Starodubova Square, 1, Dnipro, 49107, Ukraine. ORCID: 0000-0001-6139-5956. E-mail: metall729321@gmail.com<\/p>\n\n\n\n<p><strong>Kysliakov<\/strong><strong> <\/strong><strong>Volodymyr Hennadiiovych<\/strong>, Ph. D. (Tech.), Senior Researcher, Head of Department, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, Academican Starodubova Square, 1, Dnipro, 49107, Ukraine. ORCID: 0000-0002-1775-5050. E-mail: ovoch-isi@outlook.com<\/p>\n\n\n\n<p><strong>Rudenko Oleksandr Leonidovych<\/strong>, Ph. D. (Tech.), Senior Researcher, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, Academican Starodubova Square, 1, Dnipro, 49107, Ukraine. ORCID: 0000-0001-6068-9901. E-mail: ovoch-isi@outlook.com<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>MATHEMATICAL AND ANALYTICAL ANALYSIS OF THE INFLUENCE OF TECHNOLOGICAL FACTORS AND PARAMETERS ON THE EFFICIENCY OF THE PROCESS OF DESULFURIZATION OF CAST IRON WITH MAGNESIUM<\/strong><\/h2>\n\n\n\n<p><strong>Abstract. <\/strong>The purpose of the work was to make a mathematical and analytical assessment using the methods of mathematical statistics and modern computer application programs of the unit effect of temperature, initial and final sulfur content, depth of the liquid bath and mass of cast iron, mass of ladle slag, intensity of magnesium supply, consumption of gas carrier and freeboard in a ladle on the effectiveness of the desulphurization process of cast iron with magnesium. The comparison of the obtained results of mathematical and statistical processing with the results of a theoretical assessment of the influence of technological factors and parameters on the efficiency of the magnesium iron desulfurization process made it possible to assess the presence and potential opportunities for increasing the efficiency of the iron desulfurization processes implemented in different initial conditions. In order to improve technological processes of desulfurization of cast iron with magnesium, it is recommended to control and, if necessary, adjust the chemical composition and parameters of ladle slags to increase their basicity and sulfide capacity. The expediency is shown, on measures and expansion composed bank of actual data, continue their mathematical and statistical processing for clarification purposes single impact on efficiency process desulfurization cast iron initial conditions and parameters processing.<\/p>\n\n\n\n<p><strong>Key<\/strong><strong> <\/strong><strong>words: <\/strong>desulfurization, cast iron, statistical analysis, ladle, slag, mixer.<\/p>\n\n\n\n<p><strong>DOI: <\/strong><a href=\"https:\/\/doi.org\/10.52150\/2522-9117-2024-38-146-167\">https:\/\/doi.org\/10.52150\/2522-9117-2024-38-146-167<\/a><\/p>\n\n\n\n<p><strong>For citation:<\/strong> Yelisieiev, V. I., Manachyn, I. O., Molchanov, L. S., Kysliakov, V. H., &amp; Rudenko, O. L. (2024). Mathematical and analytical analysis of the influence of technological factors and parameters on the efficiency of the process of desulfurization of cast iron with magnesium. <em>Fundamental and applied problems of ferrous metallurgy<\/em>, 38, 146-167. <a href=\"https:\/\/doi.org\/10.52150\/2522-9117-2024-38-146-167\">https:\/\/doi.org\/10.52150\/2522-9117-2024-38-146-167<\/a>.<\/p>\n\n\n\n<p><strong>References<\/strong><\/p>\n\n\n\n<p>1. International Magnesium Association The Global Voice for magnesium, October 21, 1999.<\/p>\n\n\n\n<p>2. Voronova, N. A. (1980). <em>Desulfuratsyia chuhuna mahnyem<\/em>. Metallurhyia<\/p>\n\n\n\n<p>3. Shevchenko, A. F., Bolshakov, V. Y., &amp; Bashmakov, A. M. (2011). Tekhnolohyia y oborudovanye desulfuratsyy chuhuna mahnyem v bolshehruzn\u044bkh kovshakh. Naukova dumka<\/p>\n\n\n\n<p>4. Shevchenko, A. F., Manachyn, Y. A., Verhun, A. S. et al<em>. <\/em>(2017).<em> Vnepechnaia desulfuratsyia chuhuna v kovshakh. 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Hot metal desulphurization by CaCMVlg coinjection in Usiminas Steel Shop 2. In: <em>ISS Steelmaking Conference, Chicago, USA<\/em>, pp. 183 \u2013 201<\/p>\n\n\n\n<p>10. Shevchenko, A. F. (1997). <em>Razrabotka i razvitie teorii i tekhnologii protcessov vnepechnoi desulfuratcii chuguna v kovshakh vduvaniem dispergirovannykh reagentov<\/em>. D. Sc. thesis, specialty 05.16.02. Dnepropetrovsk, IChM NANU<\/p>\n\n\n\n<p>11. Zborshchik, A. M. (1995). <em>Razvitie teorii i protcessov desulfuratcii i modifitcirovaniia chuguna magniem<\/em>. D. Sc. thesis, specialty 05.16.02. Donetck, DGTU.<\/p>\n\n\n\n<p>12. Vergun, A. S. (2003). <em>Razvitie teorii i razrabotka resurso- i energosberegaiushchikh tekhnologii kovshevogo rafinirovaniia chuguna pered kislorodno-konverternoi plavkoi<\/em>. D. Sc. thesis, specialty 05.16.02. Dnepropetrovsk<\/p>\n\n\n\n<p>13. Sigarev, E. N. (2012). <em>Nauchnoe obosnovanie i razrabotka kompleksnoi energoeffektivnoi tekhnologii konverternogo proizvodstva zhelezouglerodistogo poluprodukta<\/em>. D. Sc. thesis, specialty 05.16.02. Dnepropetrovsk, IChM NMetAU<\/p>\n\n\n\n<p>14. Zborshchik, A. M. (2001). Analiz termodinamiki i kinetiki desulfuratcii chuguna magniem. <em>Stal<\/em>, (7), 17-20<\/p>\n\n\n\n<p>15. Machikin, V. I., &amp; Skladanovskii, E. N. (1979). Issledovanie desulfuratcii chuguna magniem. <em>Stal<\/em>, (4), 251-254<\/p>\n\n\n\n<p>16. Okhotskii V. B. (2001). Model desulfuratcii chuguna. Magnii. Metallurgicheskaia i gornorudnaia promyshlennost, (1), 23-25<\/p>\n\n\n\n<p>17. Diudkin, D. A., Grinberg, S. E., &amp; Marintcev, S. N. (2001). Mekhanizm desulfuratcii chuguna granulirovanym magniem. <em>Metallurg<\/em>, (4), 38-40<\/p>\n\n\n\n<p>18. Irons, G. A, &amp; Guthrie, I. L. (1981). Kinetika desulfuratcii rasplavlennogo zheleza s ispolzovaniem para magniia. <em>Metallurgical Transactions B<\/em>, (12B), 755-767<\/p>\n\n\n\n<p>19. Irons, G., &amp; Guthrie, I. (1981). Kineticheskie aspekty desulfuratcii chuguna magniem. <em>Metals Society<\/em>, (3), 114-121<\/p>\n\n\n\n<p>20. Konoplia, V. G., &amp; Plokhikh, P. A. (1985). O mekhanizme desulfuratcii chuguna pri obrabotke ego magniem. <em>Metallurgiia i koksokhimiia<\/em>, (88), 49-55<\/p>\n\n\n\n<p>21. Nosochenko, O. V., Baptizmanskii, V. I., Ivanov, E. A., Shevchenko, A. F., Dvoskin, B. V., Lonskii, A. M., &amp; Pozhivanov, M. A. (1993). Zakonomernosti desulfuratcii chuguna granulirovannym magniem. <em>Stal<\/em>, (8)<\/p>\n\n\n\n<p>22. Vergun, A. S. (2000). Mekhanizm protcessa desulfuratcii chuguna magniem. <em>Metallurgicheskaia i gornorudnaia promyshlennost<\/em>, (3), 19-2222. Verhun A.S. Mekhanyzm protsessa desulfuratsyy chuhuna mahnyem. Metallurhycheskaia y hornorudnaia prom\u044bshlennost. 2000.- \u21163. \u2013 S19-22.<\/p>\n\n\n\n<p>23. Rudenko, A. L. (2012). The Kinetics of Interfacial Transfer of Sulfur During Hot metal Treatment with. <em>The Seventh International Conference on Material Technologies and Modeling MMT \u2013 2012, Ariel Univesity Center of Samaria Ariel, Israel, August 20-23, 2012, <\/em>pp.138-149<\/p>\n\n\n\n<p>24. <em>Izuchenie zakonomernostei vzaimodeistviia kholodnogo dvukhfaznogo magniisoderzhashchego potoka s rasplavom chuguna pri istechenii na bolshikh glubinakh rafinirovaniia vanny<\/em>. (2005). Otchet No. 0106U03771. Institut chernoi metallurgii NAN Ukrainy <\/p>\n\n\n\n<p>25. Belai, G. E., Dembrovskii, V. V., &amp; Sotcenko, O. V. (1993). <em>Organizatciia metallurgicheskogo eksperimenta<\/em>. Metallurgiia<\/p>\n\n\n\n<p>26. Baptizmanskii, V. I., Iakovlev, Iu. N., &amp; Paniotov, Iu. S. (1992). <em>Organizatciia eksperimenta<\/em>.&nbsp; UMKVO<\/p>\n\n\n\n<figure class=\"wp-block-image size-large is-resized\"><a href=\"https:\/\/jrn.isi.gov.ua\/sb\/sb38\/38_146-167.pdf\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"336\" src=\"https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-1024x336.png\" alt=\"\" class=\"wp-image-3537\" style=\"width:200px\" srcset=\"https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-1024x336.png 1024w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-300x98.png 300w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-766x251.png 766w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-1536x503.png 1536w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-2048x671.png 2048w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-458x150.png 458w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-100x33.png 100w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-1068x350.png 1068w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3-788x258.png 788w, https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2023\/08\/Button3.png 180w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/a><\/figure>\n","protected":false},"excerpt":{"rendered":"<p>Yelisieiev Volodymyr Ivanovych, Ph. D. (Pys.-Math.), Senior Researcher, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, Academican Starodubova Square, 1, Dnipro, 49107, Ukraine. ORCID: 0000-0003-4999-8142. E-mail: ovoch-isi@outlook.com Manachyn Ivan Oleksandrovych, Ph. D. (Tech.), Senior Researcher, Iron and Steel Institute of Z. I. Nekrasov National Academy of Sciences of Ukraine, [&hellip;]<\/p>\n","protected":false},"author":4,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-4964","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages\/4964","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=4964"}],"version-history":[{"count":2,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages\/4964\/revisions"}],"predecessor-version":[{"id":5985,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages\/4964\/revisions\/5985"}],"wp:attachment":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=4964"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}