{"id":1907,"date":"2021-05-17T10:21:02","date_gmt":"2021-05-17T08:21:02","guid":{"rendered":"https:\/\/jrn.isi.gov.ua\/?page_id=1907"},"modified":"2023-08-12T22:40:49","modified_gmt":"2023-08-12T19:40:49","slug":"1907-2","status":"publish","type":"page","link":"https:\/\/jrn.isi.gov.ua\/?page_id=1907&lang=en","title":{"rendered":"DOI: 10.52150\/2522-9117-2020-34-229-246"},"content":{"rendered":"<p><strong><a href=\"https:\/\/jrn.isi.gov.ua\/sb\/sb34\/34%20229-246.pdf\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone wp-image-1799\" src=\"https:\/\/jrn.isi.gov.ua\/wp-content\/uploads\/2021\/01\/Button-300x99.png\" alt=\"\" width=\"200\" height=\"66\" \/><\/a><\/strong><\/p>\n<p><strong>Babachenko Alexander Ivanovich, <\/strong>Dr. Sci., (Engin.), Senior Research Scientist, Director, Iron and Steel Institute named after Z.I. Nekrasov of the NAS of Ukraine, Academican Starodubova square, 1, Dnipro, Ukraine, 49107; e-mail: a_babachenko@i.ua, ORCID 0000-0003-4710-0343<\/p>\n<p><strong>Dyomina Kateryna Hennadiivna, <\/strong>PhD (Engin.), Senior Researcher,, Iron and Steel Institute named after Z.I. Nekrasovof the NAS of Ukraine, Academican Starodubova square, 1, Dnipro, Ukraine, 49107; e-mail: katya20@ua.fm, ORCID 0000-0001-9668-8169<\/p>\n<p><strong>Kononenko Anna Andreevna, <\/strong>PhD (Engin.), Senior Researcher, Iron and Steel Institute named after Z.I. Nekrasov of the NAS of Ukraine, Academican Starodubova square, 1, Dnipro, Ukraine, 49107; e-mail: perlit@ua.fm, a_kononenko@inbox.ru\u00a0 ORCID 0000-0001-7446-4105; ORCID 0000-0001-7446-4105<\/p>\n<p><strong>Dementieva Zhanna Andriivna, <\/strong>Researcher, Iron and Steel Institute named after Z.I. Nekrasov of the NAS of Ukraine, Academican Starodubova square, 1, Dnipro, Ukraine, 49107<\/p>\n<p><strong>Safronova Elena Anatolievna<\/strong>, engineer, Institute named after Z.I. Nekrasov of the NAS of Ukraine, Academican Starodubova square, 1, Dnipro, Ukraine, 49107; ORCID 0000-0002-4032-4275<\/p>\n<h3 style=\"text-align: left;\"><strong>Research of the effect of the cooling rate during solidification of a continuously cast billet on the features of the dendritic structure of carbon steel<\/strong><\/h3>\n<p><strong>Summary.<\/strong> The analysis of the formation process of the cast structure of carbon steel grade EA1N (EN\u00a013261:\u00a02009\u00a0+\u00a0A1:\u00a02010\u00a0(\u0415)) after the completion of its crystallization with a change in a wide range of metal cooling rate during solidification of a continuously cast billet (\u0421\u0421B) with a diameter of 470\u00a0mm has been carried out. The effect of the cooling rate during the solidification of \u0421\u0421B\u00a0\u00d8\u00a0470\u00a0mm on the parameters of the chemical heterogeneity of the distribution of silicon and manganese in the microstructure of carbon steel has been shown. It has been determined that the effect of the metal cooling rate during the solidification of the investigated CCB on the size of dendritic crystals is described by the inversely proportional relationship: <em>\u0443\u00a0=\u00a0510,85\u00a0\u0445<sup>-0,156<\/sup><\/em>. With a change in the cooling rate of the metal during solidification from 10<sup>6<\/sup> \u0434\u043e 1\u00a0\u2103\u00a0\/\u00a0min, the size of the dendrites in the direction from the surface to the central layers of the CCB \u00d8\u00a0470\u00a0mm increased by ~\u00a08\u00a0times, and the density of the dendritic structure of carbon steel\u00a0EA1N decreases by 64\u00a0times. In this case, the nature of its dependence on the intensity of heat removal is the opposite nature of the change in the size of dendrites.\u00a0 It has been established that by varying the cooling rate in the range 1\u00a0\u2013\u00a010<sup>6<\/sup>\u00a0\u2103\u00a0\/\u00a0min, one can achieve a significant change in the average size and density of dendritic crystals while maintaining the constancy of the volume fraction of segregation areas of silicon and manganese ~\u00a023% in carbon steel (~\u00a00.4\u00a0%\u00a0wt.\u00a0C). The results of X-ray spectral analysis of samples of \u0421\u0421B\u00a0\u00d8\u00a0470\u00a0mm made of carbon steel grade EA1N showed that the maximum content of silicon and manganese is characteristic of the former spaces between the first-order dendritic branches, their minimum content is for the former dendritic branches. At the same time, the amount of these elements in steel microvolumes, which are the former spaces between the second-order dendritic branches, is on average 50\u00a0% more than in the former dendritic branches. It has been determined that in the entire investigated range of cooling rates 1\u00a0\u2013\u00a010<sup>6<\/sup>\u00a0\u2103\u00a0\/\u00a0min, the coefficients of dendritic segregation <em>\u041a<sub>\u0434<\/sub><\/em><em><sup>I<\/sup><\/em> and <em>\u041a<sub>\u0434<\/sub><\/em><em><sup>II<\/sup><\/em> of silicon and manganese change insignificantly and amount to 1.8-1.9 and 1.5 for <em>\u041a<sub>\u0434<\/sub><\/em><em><sup>I<\/sup><\/em> and <em>\u041a<sub>\u0434<\/sub><\/em><em><sup>II<\/sup><\/em>, respectively. In this case, the values of the coefficients <em>\u041a<sub>\u0434<\/sub><\/em><em><sup>I<\/sup><\/em> and <em>\u041a<sub>\u0434<\/sub><\/em><em><sup>II<\/sup><\/em> for both elements are practically constant in both pearlite and ferrite. It has been proven that both silicon and manganese have high diffusion mobility only at sufficiently high temperatures, when steel is in a solid-liquid state. Based on the results of X-ray microanalysis, it has been established that the heterogeneity of the distribution of chemical elements, which is formed as a result of dendritic segregation of silicon and manganese, is the primary and constant component of the microstructure of carbon steel.<br \/>\n<strong>Keywords: <\/strong>carbon steel, dendritic structure, liquation, continuously cast billet<\/p>\n<p><strong>Reference<\/strong><\/p>\n<p>Chalmers\u00a0B. <em>Teoriya zatverdevaniya<\/em> [Principles of Solidification] \/ B.\u00a0Chalmers. \u2013 Moscow:\u00a0Metallurgiya, 1968. \u2013 287\u00a0p. [in Russian].<\/p>\n<p>Flemings\u00a0M. <em>Processy` zatverdevaniya<\/em> [Solidification Processing] \/ M.\u00a0Fleming. \u2013 Moscow:\u00a0Mir, 1977. \u2013 423\u00a0p. [in Russian].<\/p>\n<p>Golikov\u00a0I.N. <em>Dendritnaya likvaciya v stalyax i splavax<\/em> [Dendritic segregation in steels and alloys] \/ I.N.\u00a0Golikov, O.B.\u00a0Maslenkov. \u2013 Moscow:\u00a0Metallurgiya, 1977. \u2013 224\u00a0p. [in Russian].<\/p>\n<p>Won\u00a0Y.-M., Thomas\u00a0B.S. <em>Simple Model of Microsegregation during Solidification of Steels<\/em> \/ Y.-M.\u00a0Won, V.S.\u00a0Thomas \/\/ Metallurgical and Material Transactions. \u2013 2001. \u2013 Vol. 32A, July. \u2013 pp.\u00a01755\u00a0\u2013\u00a01767. [in English]. <a href=\"https:\/\/doi.org\/10.1007\/s11661-001-0152-4\">https:\/\/doi.org\/10.1007\/s11661-001-0152-4<\/a><\/p>\n<p>Papapetrou\u00a0A. <em>Untersuchungen \u00fcber dendritisches Wachstum von Kristallen<\/em> \/ A.\u00a0Papapetrou \/\/ Zeitschrift f\u00fcr Kristallographie. \u2013 1935. \u2013 Vol. 92: Issue\u00a01 (Dec.). \u2013 S.\u00a089-129. 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[in Russian].<\/p>\n<p>Salty`kov\u00a0S.A. <em>Stereometricheskaya<\/em> <em>metallografiya<\/em> [[Stereometric metallography] \/ S.A.\u00a0Salty`kov \u2013 Moscow:\u00a0Metallurgiya, 1976. \u2013 271\u00a0p. [in Russian].<\/p>\n<p>Dyomina\u00a0E.G. <em>Analiz<\/em> <em>prorabaty<\/em><em>`<\/em><em>vaemosti<\/em> <em>struktury<\/em><em>` <\/em><em>stali<\/em><em> 09<\/em><em>G<\/em><em>2<\/em><em>S<\/em> <em>v<\/em> <em>processe<\/em> <em>goryachej<\/em> <em>prokatki<\/em> <em>neprery<\/em><em>`<\/em><em>vnolitoj<\/em> <em>zagotovki<\/em> \/ E.G.\u00a0Dyomina, Zh.A.\u00a0Dement`eva, A.S.\u00a0Mirgorodskaya, D.V.\u00a0Gunchenko \/\/ Nauka \u0456 metalurg\u0456ya. Elektronne vidannya zb\u0456rky naukovyx pracz`. \u2013 Dn\u0456pro,\u00a02018. \u2013 Vyp. 2. \u2013 pp.\u00a04\u00a0\u2013\u00a018. [in Russian].<\/p>\n<p><em>Radius atoma, spravochnaya tablicza [e`lektronny`j resurs]. Formuly` i raschyoty` online f\u00a0(x,\u00a0y,\u00a0z).ru.<\/em> Rezhim dostupa: <a href=\"https:\/\/www.fxyz\/\u0441\u043f\u0440\u0430\u0432\u043e\u0447\u043d\u044b\u0435_\u0434\u0430\u043d\u043d\u044b\u0435\/\u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430_\u0430\u0442\u043e\u043c\u043e\u0432_\u0432\u0435\u0449\u0435\u0441\u0442\u0432\/\u0440\u0430\u0434\u0438\u0443\u0441\u044b%20_\u0430\u0442\u043e\u043c\u043e\u0432_\u044d\u043b\u0435\u043c\u0435\u043d\u0442\u043e\u0432\/\">https:\/\/www.fxyz\/\u0441\u043f\u0440\u0430\u0432\u043e\u0447\u043d\u044b\u0435_\u0434\u0430\u043d\u043d\u044b\u0435\/\u0441\u0432\u043e\u0439\u0441\u0442\u0432\u0430_\u0430\u0442\u043e\u043c\u043e\u0432_\u0432\u0435\u0449\u0435\u0441\u0442\u0432\/\u0440\u0430\u0434\u0438\u0443\u0441\u044b _\u0430\u0442\u043e\u043c\u043e\u0432_\u044d\u043b\u0435\u043c\u0435\u043d\u0442\u043e\u0432\/<\/a>. [in Russian].<\/p>\n<p>Oikawa\u00a0H. <em>Review on lattice diffusion of substitutional impurities in iron. A summary report<\/em> \/ Hiroshi Oikawa \/\/ Technol. Rep. Tohoku Univ. \u2013 1982. \u2013 Vol. 47. \u2013 No. 2. \u2013 pp. 215 \u2013 224. [in English].<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Babachenko Alexander Ivanovich, Dr. Sci., (Engin.), Senior Research Scientist, Director, Iron and Steel Institute named after Z.I. Nekrasov of the NAS of Ukraine, Academican Starodubova square, 1, Dnipro, Ukraine, 49107; e-mail: a_babachenko@i.ua, ORCID 0000-0003-4710-0343 Dyomina Kateryna Hennadiivna, PhD (Engin.), Senior Researcher,, Iron and Steel Institute named after Z.I. Nekrasovof the NAS of Ukraine, Academican Starodubova [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-1907","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages\/1907","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1907"}],"version-history":[{"count":4,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages\/1907\/revisions"}],"predecessor-version":[{"id":3967,"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=\/wp\/v2\/pages\/1907\/revisions\/3967"}],"wp:attachment":[{"href":"https:\/\/jrn.isi.gov.ua\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1907"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}